860 KF Thermoprep - simple, safe and precise sample preparation

20 Oct 2008
Regina Schlink
Manufacturing / Processing

The 860 KF Thermoprep is the new Metrohm instrument for thermal sample preparation in Karl Fischer titration. It can be combined with a wide range of titrators for volumetric and coulometric water determination.

Benefits of thermal sample preparation
The 860 KF Thermoprep heats the substance under investigation in a hermetically sealed vessel. The moisture liberated from the sample is transferred via a carrier gas stream into the titration cell where it is determined. This means that the 860 KF Thermoprep is the ideal instrument for reliable analysis of 'difficult' samples, such as plastics or salts, which release their water very slowly or only at elevated temperatures and are therefore not suitable for direct KF titration. As the sample does not enter the titration cell, side reactions with the KF reagents used are excluded.

Simple operation, high occupational safety
Thanks to the clearly arranged menu navigation, all parameters can be set with just a few keys to suit individual requirements. The sophisticated design of the 860 KF Thermoprep prevents the needle from descending outside the septum. In most cases the oven method requires no toxic solvents, so no harmful solvent vapors can escape into the lab.

Precise results made easy
The 860 KF Thermoprep ensures identical analysis conditions for each sample. Vessels tightly sealed with a PTFE septum (headspace vials) guarantee a constant, unadulterated water content even after longer periods of storage. The heated transfer tubing prevents water vapour condensation and ensures that all the moisture arrives in the titration cell and is determined there.

860 KF Thermoprep

Metrohm AG

Thermal sample preparation in Karl Fischer titration. For various reasons many substances are not suitable for a direct Karl Fischer titration: – They release their water only slowly – The water is released at high temperatures only – The substances are poorly soluble in alcohols – They undergo side reactions with KF reagents – They contaminate the titration cell or the electrodes By using the KF oven method the above-mentioned problems can be avoided. The substance under investigation is heated in a hermetically sealed vial in the oven. The water vapor released is transferred to the titration cell by a carrier gas. This means that no noxious solubilizers have to be used, side reactions as well as matrix effects are absent and the contamination of the titration cell is avoided. Depending on the sample’s water content, the determination can be carried out either by coulometric or volumetric Karl Fischer titration.

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860 KF Thermoprep - simple, safe and precise sample preparation